Sahih Muslim Book 4, Hadith Number 814.
Chapter : Blessing on the Prophet (may peace be upon him) after Tashahhud.
Abu Harare reported: The Messenger of Allah (may peace be upon him) said: When anyone amongst you utters Amin and the angels In the heaven also utter Amin and (the Amin) of the one synchronises with (that of) the other, all his previous sins are pardoned.